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What (who) is 2,3-sigmatropic rearrangement - definition
2,3-sigmatropic rearrangement
CLASS OF CHEMICAL REACTION
2,3-sigmatropic shift
2,3-Sigmatropic rearrangements are a type of sigmatropic rearrangements and can be classified into two types. Rearrangements of allylic sulfoxides, amine oxides, selenoxides are neutral.
2,3-Wittig rearrangement
CHEMICAL REACTION
User:Mevans86/2,3-Wittig rearrangement; User:OrganicReactions/2,3-Wittig rearrangement
The [2,3]-Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. Because the reaction is concerted, it exhibits a high degree of stereocontrol, and can be employed early in a synthetic route to establish stereochemistry.
2,3-dihydroxybenzoate 2,3-dioxygenase
CLASS OF ENZYMES
EC 1.13.11.28; 2,3-dihydroxybenzoate:oxygen 2,3-oxidoreductase (decyclizing)
In enzymology, a 2,3-dihydroxybenzoate 2,3-dioxygenase () is an enzyme that catalyzes the chemical reaction
